Novel polymerizable mono- and divalent quaternary ammonium cationic surfactants .1. Synthesis, structural characterization and homopolymerization

被引：32

作者：

Joynes, D ^{[1
]}

Sherrington, DC ^{[1
]}

机构：

[1] UNIV STRATHCLYDE,DEPT PURE & APPL CHEM,GLASGOW G1 1XL,LANARK,SCOTLAND

来源：

POLYMER | 1996年 / 37卷 / 08期

关键词：

polymerizable surfactant; divalent surfactant;

D O I：

10.1016/0032-3861(96)81144-X

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 [高分子化学与物理]; 080501 [材料物理与化学]; 081704 [应用化学];

摘要：

Eight novel polymerizable monovalent quaternary ammonium bromide surfactants and five model nonpolymerizable structurally analogous surfactants have been synthesized. Methylation of free amine groups in six of the polymerizable monoquaternary ammonium species has yielded the corresponding divalent diquaternary ammonium dibromide surfactants, and likewise, five non-polymerizable divalent diquaternary ammonium dibromides have been prepared. All the new molecules have been characterized structurally by elemental microanalysis and H-1 nuclear magnetic resonance spectroscopy. The solubility, melting behaviour and homopolymerizability of the monomers have been evaluated and the results discussed with those of structurally related systems already in the literature. Copyright (C) 1996 Elsevier Science Ltd.

引用

页码：1453 / 1462

页数：10

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