Electronic properties of neutral dyes in the channels of zeolite L:: A combined spectroscopic and quantum chemical study

被引：19

作者：

Bussemer, Beate ^{[1
]}

Munsel, Dirk ^{[1
]}

Wuenscher, Heike ^{[1
]}

Mohr, Gerhard J. ^{[1
]}

Grummt, Ulrich-Walter ^{[1
]}

机构：

[1] Univ Jena, Inst Phys Chem, D-07743 Jena, Germany

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2007年 / 111卷 / 01期

关键词：

D O I：

10.1021/jp064986w

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Three low molecular weight model compounds for poly(phenylene-ethynylene)s were inserted into the channels of zeolite L by using gas phase insertion. The absorption and emission spectra in solution and dye/zeolite L are reported. Two compounds show emission properties in zeolite L comparable to that in solution. In contrast, the bipyridine containing compound shows a red shift toward longer excitation wavelengths. Matrix rank analysis of the emission spectra gave three contributing species. Quantum chemical calculations provide different conformations depending on the Si/Al distribution of the framework and the extraframework cations and attached protons.

引用

页码：8 / 15

页数：8

共 34 条

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