Electrical conductivity studies in hydrogels

被引:239
作者
Pissis, P
Kyritsis, A
机构
关键词
hydrogels; ac conductivity; dc conductivity; complex impedance; electric modulus; fragility;
D O I
10.1016/S0167-2738(97)00074-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The electrical conductivity of poly(hydroxyethyl acrylate) PHEA, hydrogels was studied by means of dielectric relaxation spectroscopy in wide ranges of frequency (5 Hz-2 GHz), temperature (173-363 K) and water content (0.065-0.46 g of water per gram of dry material). The data are analyzed within the formalisms of permittivity, impedance and modulus. The results are discussed in terms of temperature- and water-induced effects, shape of the response, fragility and homogeneous-heterogeneous nature of the hydrogels.
引用
收藏
页码:105 / 113
页数:9
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