Redox-active polyiron complexes with tetra(ethynylphenyl) ethene and [2,2]paracyclophane spacers containing ethynylphenyl units: extension to higher dimensional molecular wire

被引：31

作者：

Tanaka, Yuya ^{[1
]}

Ozawa, Takehiro ^{[1
]}

Inagaki, Akiko ^{[1
]}

Akita, Munetaka ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

DALTON TRANSACTIONS | 2007年 / 09期

关键词：

DICARBIDE CLUSTER COMPOUNDS; CRYSTAL-STRUCTURE; BUILDING-BLOCKS; METAL-COMPLEXES; CARBON; CHAIN; IRON; POLYYNEDIYL; CENTERS;

D O I：

10.1039/b614803d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Redox active polyiron complexes with higher dimensional spacers, the tetrairon complex with the two-dimensional tetra( ethynylphenyl) ethene spacer, (C=C)[p-C6H4-C = C-FeCp*(dppe)]4, and the diiron complex with the three-dimensional spacer (pseudo-m-[2,2] paracyclophane)[C equivalent to C-FeCp*(dppe)](2), are prepared, and their performance as molecular wires is evaluated on the basis of their comproportionation constants for the mixed valence state.

引用

收藏

页码：928 / 933

页数：6

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