Layer-by-layer preparation of polyelectrolyte multilayer membranes for separation

被引:293
作者
Joseph, Nithya [1 ]
Ahmadiannamini, Pejman [1 ]
Hoogenboom, Richard [2 ]
Vankelecom, Ivo. F. J. [1 ]
机构
[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, Fac Biosci Engn, B-3001 Louvain, Belgium
[2] Univ Ghent, Dept Organ Chem, Supramol Chem Grp, Fac Sci, B-9000 Ghent, Belgium
关键词
SOLVENT-RESISTANT NANOFILTRATION; SELECTIVE ION-TRANSPORT; PERVAPORATION SEPARATION; MECHANICAL-PROPERTIES; THIN-FILMS; OSMOSIS MEMBRANES; PRUSSIAN BLUE; GROWTH REGIME; HIGH-FLUX; ULTRATHIN;
D O I
10.1039/c3py01262j
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polymer membranes provide a highly promising platform for the development of an efficient and sustainable technique for separation. Ideally such membranes combine a high flux with a high selectivity requiring thin defect-free membranes. The layer by layer (LBL) assembly technique has proven to be a versatile and simple method for the fabrication of very thin polyelectrolyte multilayers making it highly suitable for the preparation of separation membranes. Recent developments in this field related to membrane preparation and their applications in separation processes are presented and discussed in this review. An overview of the different fabrication techniques of such membranes will be first provided. In addition, the formation mechanism and the parameters that can be varied to tune the properties of the membranes will be discussed. Finally, the potential applications of these membranes in different separation areas such as pervaporation, nanofiltration, solvent resistant nanofiltration, reverse osmosis, gas separation and forward osmosis will be addressed.
引用
收藏
页码:1817 / 1831
页数:15
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