Structural characterization of the 'lantern-shaped' platinum(III) complex [Pt2Cl2{N(H)C(But)O}4]

被引：18

作者：

Dolmella, A

Intini, FP

Pacifico, C

Padovano, G

Natile, G

机构：

[1] Univ Bari, Dipartimento Farmacochim, I-70125 Bari, Italy

[2] Univ Padua, Dipartimento Sci Farmaceut, I-35131 Padua, Italy

[3] Univ Bari, Dipartimento Biol & Chim Agroforestale Ambientale, I-70125 Bari, Italy

来源：

POLYHEDRON | 2002年 / 21卷 / 03期

关键词：

platinum(III) compounds; lantern-type complexes; amidate bridging ligands; X-ray structure;

D O I：

10.1016/S0277-5387(01)00992-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of a new platinum(III) 'lantern-shaped' complex with amidate bridging ligands, [Pt2Cl2{N(H)C(Bu-t)O}(4)] (1), is described. Complex I has been structurally characterized by X-ray diffraction and compared with the related compound [Pt2I2{N(H)C(Me)O}(4)] (2). The two complexes exhibit very short N...O bite distances which are similar in the two cases but the Pt(III)-Pt(III) distance is significantly shorter in 1 than in 2. (C) 2002 Elsevier Science Ltd. All rights reserved.

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页码：275 / 280

页数：6

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