Chemical polymerization of pyrrole with disulfide structure and the application to lithium secondary batteries

被引：46

作者：

Amaike, M ^{[1
]}

Iihama, T ^{[1
]}

机构：

[1] Nippon Soda Co Ltd, R&D Lab High Performance Mat, Ichihara, Chiba 2900045, Japan

来源：

SYNTHETIC METALS | 2006年 / 156卷 / 2-4期

关键词：

polypyrrole; disulfide; chemical-oxidative polymerization; lithium battery; conductivity;

D O I：

10.1016/j.synthmet.2005.11.007

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

An intramolecular cyclic disulfide-containing polypyrrole was prepared by the chemical-oxidative polymerization of 4,6-dihydro-1H-[1,2]dithiino[4,5-c]pyrrole (MPY), and the electrical properties were investigated as the cathode active material in lithium secondary batteries. Oxidizing agents and solvents for the chemical-oxidative polymerization were examined to prevent over-oxidation of the polypyrrole backbone. The conductivity of poly(MPY), the polymer prepared using FeCl3 in ethylene glycol, was around 10(-4) S/cm. Poly(MPY) showed very little over-oxidation, good redox properties, and a high discharge capacity of 398 mAh/g based on the redox response of the disulfide. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：239 / 243

页数：5

共 32 条

[1]

[Anonymous], SYNTH METALS, DOI DOI 10.1016/0379-6779(89)90610-3

[2] Conducting polymer artificial muscles [J].

Baughman, RH .

SYNTHETIC METALS, 1996, 78 (03) :339-353

[3] X-ray photoelectron spectroscopy sulfur 2p study of organic thiol and disulfide binding interactions with gold surfaces [J].

Castner, DG ;

Hinds, K ;

Grainger, DW .

LANGMUIR, 1996, 12 (21) :5083-5086

[4] Synthesis of disulfide-containing aniline and copolymerization with aniline [J].

Cho, JS ;

Sato, S ;

Takeoka, S ;

Tsuchida, E .

MACROMOLECULES, 2001, 34 (09) :2751-2756

[5] Potential-induced enantioselective uptake of amino acid into molecularly imprinted overoxidized polypyrrole [J].

Deore, B ;

Chen, ZD ;

Nagaoka, T .

ANALYTICAL CHEMISTRY, 2000, 72 (17) :3989-3994

[6] Infrared and Raman spectroscopic studies of the electrochemical oxidative degradation of polypyrrole [J].

Ghosh, S ;

Bowmaker, GA ;

Cooney, RP ;

Seakins, JM .

SYNTHETIC METALS, 1998, 95 (01) :63-67

[7] Electrochemical behaviors of naphtho [1,8-cd][1,2]dithiol, dibenzo[c,e][1,2]dithiin, and naphtho[1,8-cd:4,5-c′d′]bis[1,2]dithiol their application to lithium polymer batteries [J].

Inamasu, T ;

Yoshitoku, D ;

Sumi-otorii, Y ;

Tani, H ;

Ono, N .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (01) :A128-A132

[8] 3RD-GENERATION AMPEROMETRIC BIOSENSOR FOR GLUCOSE - POLYPYRROLE DEPOSITED WITHIN A MATRIX OF UNIFORM LATEX-PARTICLES AS MEDIATOR [J].

KOOPAL, CGJ ;

FEITERS, MC ;

NOLTE, RJM ;

DERUITER, B ;

SCHASFOORT, RBM .

BIOELECTROCHEMISTRY AND BIOENERGETICS, 1992, 29 (02) :159-175

[9] THE APPLICATION OF POLYPYRROLE AS COUNTERELECTRODE IN ELECTROLYTIC CAPACITORS [J].

KRINGS, LHM ;

HAVINGA, EE ;

DONKERS, JJTM ;

VORK, FTA .

SYNTHETIC METALS, 1993, 54 (1-3) :453-459

[10] AN ALUMINUM SOLID ELECTROLYTIC CAPACITOR WITH AN ELECTROCONDUCTING-POLYMER ELECTROLYTE [J].

KUDOH, Y ;

TSUCHIYA, S ;

KOJIMA, T ;

FUKUYAMA, M ;

YOSHIMURA, S .

SYNTHETIC METALS, 1991, 41 (03) :1133-1136

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