Selectivity in the self-assembly of directional helicates

被引：20

作者：

Constable, EC

Heirtzler, FR

Neuburger, M

Zehnder, M

机构：

[1] Inst. für Anorganische Chemie, CH-4056 Basel

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 08期

关键词：

D O I：

10.1039/cc9960000933

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the asymmetric 2,2':6',2 '':6 '',2 triple prime-quaterpyridine 3c with [Cu(MeCN)(4)][PF6] gives exclusively the head-to-heap isomer of the double helical species [Cu-2(3c)(2)](2+).

引用

页码：933 / 934

页数：2

共 12 条

[1] INVERSE RELATIONSHIP BETWEEN THE KINETIC AND THERMODYNAMIC STABILITIES OF THE MISDIRECTED LIGAND COMPLEXES DELTA/LAMBDA-(DELTA/LAMBDA-1,1'-BIISOQUINOLINE)BIS(2,2'-BIPYRIDINE)METAL(II) (METAL=RUTHENIUM, OSMIUM) [J].

ASHBY, MT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (07) :2000-2007

[2] HIGHER OLIGOPYRIDINES AS A STRUCTURAL MOTIF IN METALLOSUPRAMOLECULAR CHEMISTRY [J].

CONSTABLE, EC .

PROGRESS IN INORGANIC CHEMISTRY, VOL 42, 1994, 42 :67-138

[3] SELF-ASSEMBLY OF DOUBLE-HELICAL COMPLEXES OF 2,2'-6',2''-6'',2'''-QUATERPYRIDINE (QTPY) - THE X-RAY CRYSTAL-STRUCTURES OF [CU2(QTPY)2][PF6]2 AND [AG2(QTPY)2][BF4]2 [J].

CONSTABLE, EC ;

HANNON, MJ ;

MARTIN, A ;

RAITHBY, PR ;

TOCHER, DA .

POLYHEDRON, 1992, 11 (22) :2967-2971

[4] DIRECTIONAL LIGANDS IN HELICATE SELF-ASSEMBLY [J].

CONSTABLE, EC ;

HEIRTZLER, FR ;

NEUBURGER, M ;

ZEHNDER, M .

SUPRAMOLECULAR CHEMISTRY, 1995, 5 (03) :197-200

[5] OLIGOPYRIDINES AS HELICATING LIGANDS [J].

CONSTABLE, EC .

TETRAHEDRON, 1992, 48 (46) :10013-10059

[6] AN IMPROVED, 2-STEP SYNTHESIS OF 2,2'-6',2''-TERPYRIDINE [J].

JAMESON, DL ;

GUISE, LE .

TETRAHEDRON LETTERS, 1991, 32 (18) :1999-2002

[7]

Lehn J. M., 1995, SUPRAMOLECULAR CHEM

[8]

PEREC V, 1994, INT S NEW MACR ARCH, V77

[9] METAL ION-INDUCED SELF-ASSEMBLY OF FUNCTIONALIZED 2,6-OLIGOPYRIDINES .2. COPPER-CONTAINING DOUBLE-STRANDED HELICATES DERIVED FROM FUNCTIONALIZED QUATERPYRIDINE AND QUINQUEPYRIDINE - REDOX STATE-INDUCED TRANSFORMATIONS AND ELECTRON COMMUNICATION IN MIXED-VALENCE SYSTEMS [J].

POTTS, KT ;

KESHAVARZK, M ;

THAM, FS ;

ABRUNA, HD ;

ARANA, CR .

INORGANIC CHEMISTRY, 1993, 32 (20) :4422-4435

[10] DIASTEREOISOMERIC FORMS OF LIGAND-BRIDGED DIMETALLIC DIRUTHENIUM(II) AND RUTHENIUM(II)-OSMIUM(II) SPECIES CONTAINING BIDENTATE POLYPYRIDYL LIGANDS [J].

REITSMA, DA ;

KEENE, FR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (18) :2859-2860

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