A sodalite-like framework based on octacyanomolybdate and neodymium with guest methanol molecules and neodymium octahydrate ions

被引：84

作者：

Wang, Zhao-Xi

Shen, Xiao-Fei

Wang, Jun

Zhang, Peng

Li, Yi-Zhi

Nfor, Emmanuel N.

Song, You ^{[1
]}

Ohkoshi, Shin-ichi

Hashimoto, Kazuhito

You, Xiao-Zeng

机构：

[1] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[3] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 20期

关键词：

coordination polymers; cyanides; lanthanides; magnetic properties; zeolite analogues;

D O I：

10.1002/anie.200600455

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heavy-metal sodalite: NdIII reacts with [MoV(CN) 8]3- in methanol to form a new 3D framework consisting of cyanide-bridged NdIII and MoIV ions. The anionic framework (red and blue in the picture) has a cage structure similar to that of the zeolite sodalite and contains hexagonal channels filled by methanol molecules and [NdIIICH2O)8]3+ ions (green spheres). (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3287 / 3291

页数：5

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