Mineralomimetic sodalite- and muscovite-type coordination frameworks. Dynamic crystal-to-crystal interconversion processes sensitive to ion pair recognition

被引：71

作者：

Barea, E

Navarro, JAR

Salas, JM

Masciocchi, N

Galli, S

Sironi, A

机构：

[1] Univ Granada, Dept Quim Inorgan, E-18071 Granada, Spain

[2] CNR, ISTM, I-20133 Milan, Italy

[3] Univ Milan, Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy

[4] Univ Insubria, Dipartimento Sci Chim Fis & Matemat, I-22100 Como, Italy

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 10期

关键词：

D O I：

10.1021/ja039472e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A flexible sodalite-type metal organic framework [Cu(pyrimidine-2-olate)2]n (1R) is obtained in a self-assembly process involving Cu2+ ions and pyrimidine-2-olate ligands. 1R suffers a series of sequential and reversible structural changes upon solid?liquid sorption processes of metal nitrates. The 1C-to-1O transformation occurs only with large cations. Copyright © 2004 American Chemical Society.

引用

页码：3014 / 3015

页数：2

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