Production of tungsten oxide coatings, via sol-gel processing of tungsten anion solutions

被引:21
作者
Baker, AP [1 ]
Hodgson, SNB
Edirisinghe, MJ
机构
[1] Loughborough Univ Technol, Inst Polymer Technol & Mat Engn, Loughborough LE11 3TU, Leics, England
[2] Univ London Queen Mary & Westfield Coll, Dept Mat, London E1 4NS, England
关键词
sol-gel; tungsten oxide;
D O I
10.1016/S0257-8972(01)01673-5
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
An investigation has been carried out into the production of tungsten oxide coatings from tungstic chloride and tungstic acid precursors, via a sol-gel type process, using various combinations of ethanediol and block co-polymers as stabilising additives to achieve microstructural control. The products were characterised by scanning electron microscopy, X-ray diffraction, FTIR spectroscopy and thermal analysis, with colour changes investigated by UV/Vis spectroscopy. Strongly photochromic transparent coatings were successfully prepared by the reaction of tungstic acid under basic conditions in the presence of ethanediol. (C) 2002 Elsevier Science B.V All rights reserved.
引用
收藏
页码:184 / 193
页数:10
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