Preparation and characterization of titanocene silyl hydrides [Cp2Ti(mu-HSiH2)](2) and [Cp2Ti(mu-HSiH2)(mu-H)TiCp2]

被引：16

作者：

Hao, LJ

Lebuis, AM

Harrod, JF

Samuel, E

机构：

[1] MCGILL UNIV,DEPT CHEM,MONTREAL,PQ H3A 2K6,CANADA

[2] ENSCP,LAB CHIM ORGANOMET,CNRS,URA 403,F-75005 PARIS,FRANCE

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 22期

关键词：

D O I：

10.1039/a705102f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of a complex previously assigned as [Cp2Ti(mu-SiH2)](2) is shown to be [Cp2Ti(mu-H-SiH2)](2).

引用

页码：2193 / 2194

页数：2

共 14 条

[1] POLYMERIZATION OF PRIMARY SILANES TO LINEAR POLYSILANES CATALYZED BY TITANOCENE DERIVATIVES
AITKEN, C
HARROD, JF
SAMUEL, E
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 279 (1-2) : C11 - C13
[2] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF AN UNUSUAL SILYLZIRCONIUM HYDRIDE COMPLEX
AITKEN, C
HARROD, JF
SAMUEL, E
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1986, 64 (08): : 1677 - 1679
[3] IDENTIFICATION OF SOME INTERMEDIATES IN THE TITANOCENE-CATALYZED DEHYDROGENATIVE COUPLING OF PRIMARY ORGANOSILANES
AITKEN, CT
HARROD, JF
SAMUEL, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (14) : 4059 - 4066
[4] COREY JY, 1995, ADV SILICON CHEM, V1, P327
[5] SILYLTITANOCENE COMPLEXES AS CATALYSTS FOR THE HYDROGENATION, ISOMERIZATION, AND HYDROSILATION OF OLEFINS
HARROD, JF
YUN, SS
[J]. ORGANOMETALLICS, 1987, 6 (07) : 1381 - 1387
[6] THEORETICAL-STUDY OF CP2TI(H)(SIH3) AND CP2TISIH2 AND THEIR POSSIBLE ROLE IN THE POLYMERIZATION OF PRIMARY ORGANOSILANES
HARROD, JF
ZIEGLER, T
TSCHINKE, V
[J]. ORGANOMETALLICS, 1990, 9 (04) : 897 - 902
[7] HARROD JF, 1988, ACS S SERIES, V360, pCH7
[8] PREPARATION AND CRYSTAL-STRUCTURE OF TETRAKIS(PI-CYCLOPENTADIENYL)-DI-MU-SILYLENO-DITITANIUM [(C5H5)2TISIH2]2
HENCKEN, G
WEISS, E
[J]. CHEMISCHE BERICHTE-RECUEIL, 1973, 106 (06): : 1747 - 1751
[9] CRYSTAL-STRUCTURES OF CYCLOHETEROPENTASILANES (ETA-5-CP)2TI(SIPH2)5 AND O(SIPH2)5
IGONIN, VA
OVCHINNIKOV, YE
DEMENTEV, VV
SHKLOVER, VE
TIMOFEEVA, TV
FRUNZE, TM
STRUCHKOV, YT
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 371 (02) : 187 - 196
[10] Marciniec B., 1996, APPL HOMOGENEOUS CAT, V1, P487

← 1 2 →