Triplet-to-singlet exciton formation in poly(p-phenylene-vinylene) light-emitting diodes -: art. no. 036601

被引:48
作者
Lin, LC
Meng, HF [1 ]
Shy, JT
Horng, SF
Yu, LS
Chen, CH
Liaw, HH
Huang, CC
Peng, KY
Chen, SA
机构
[1] Natl Chiao Tung Univ, Inst Phys, Hsinchu 300, Taiwan
[2] Natl Tsing Hua Univ, Dept Elect Engn, Hsinchu 300, Taiwan
[3] Natl Tsing Hua Univ, Dept Phys, Hsinchu 300, Taiwan
[4] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu 300, Taiwan
关键词
D O I
10.1103/PhysRevLett.90.036601
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The triplet to singlet exciton formation ratio in a MEH-PPV light-emitting diode is measured by comparing the triplet-induced absorptions with optical and electric excitations at the same singlet exciton density. The ratio is a strong universal decreasing function of the averaged electric field. Using 4 ns for singlet to triplet intersystem crossing time, the ratio is significantly larger than the spin-independent value 3 at intermediate field but is reduced to about 2 for higher field.
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页数:4
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