Model for Elastic Relaxation Phenomena in Finite 2D Hexagonal Molecular Lattices

被引:128
作者
Enachescu, Cristian [1 ]
Stoleriu, Laurentiu [1 ]
Stancu, Alexandru [1 ]
Hauser, Andreas [2 ]
机构
[1] Alexandru Ioan Cuza Univ, Dept Phys, Iasi, Romania
[2] Univ Geneva, Dept Chim Phys, CH-1211 Geneva 4, Switzerland
基金
瑞士国家科学基金会;
关键词
SPIN-TRANSITION; HYSTERESIS; DYNAMICS;
D O I
10.1103/PhysRevLett.102.257204
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The relaxation in a spin transition compound is modeled on the basis of molecules interacting by the way of connecting springs and situated in a bidimensional open boundary hexagonal lattice. The switch of individual molecules is randomly checked using a standard Monte Carlo procedure. The switching probability depends on the energy gap between the two states in the absence of interactions and on the elongations of the nearest springs. The main characteristics of the experimental relaxation curves are reproduced and clustering and nucleation phenomena are detected.
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页数:4
相关论文
共 28 条
[1]   One-dimensional Ising-like systems: an analytical investigation of the static and dynamic properties, applied to spin-crossover relaxation [J].
Boukheddaden, K ;
Linares, J ;
Spiering, H ;
Varret, F .
EUROPEAN PHYSICAL JOURNAL B, 2000, 15 (02) :317-326
[2]   Bistable spin-crossover nanoparticles showing magnetic thermal hysteresis near room temperature [J].
Coronado, Eugenio ;
Galan-Mascaros, Jose Ramon ;
Monrabal-Capilla, Maria ;
Garcia-Martinez, Javier ;
Pardo-Ibanez, Pablo .
ADVANCED MATERIALS, 2007, 19 (10) :1359-+
[3]   First-order reversal curves analysis of rate-dependent hysteresis: The example of light-induced thermal hysteresis in a spin-crossover solid [J].
Enachescu, C ;
Tanasa, R ;
Stancu, A ;
Varret, F ;
Linares, J ;
Codjovi, E .
PHYSICAL REVIEW B, 2005, 72 (05)
[4]   Static and light induced hysteresis in spin-crossover compounds: experimental data and application of Preisach-type models [J].
Enachescu, C ;
Machado, HC ;
Menendez, N ;
Codjovi, E ;
Linares, J ;
Varret, F ;
Stancu, A .
PHYSICA B-CONDENSED MATTER, 2001, 306 (1-4) :155-160
[5]   Single laser pulse induces spin state transition within the hysteresis loop of an Iron compound [J].
Freysz, E ;
Montant, S ;
Létard, S ;
Létard, JF .
CHEMICAL PHYSICS LETTERS, 2004, 394 (4-6) :318-323
[6]  
GEAR CW, 1971, NUMERICAL INITIAL VA
[7]   HIGH-SPIN-]LOW-SPIN RELAXATION KINETICS AND COOPERATIVE EFFECTS IN THE [FE(1-PROPYLTETRAZOLE)6](BF4)2 AND [ZN1-XFEX(1-PROPYLTETRAZOLE)6](BF4)2 SPIN-CROSSOVER SYSTEMS [J].
HAUSER, A ;
GUTLICH, P ;
SPIERING, H .
INORGANIC CHEMISTRY, 1986, 25 (23) :4245-4248
[8]  
Hauser A, 1999, COORDIN CHEM REV, V190, P471
[9]   Pressure study of the thermal spin transition and the high-spin->low-spin relaxation in the R(3)over-bar and P(1)over-bar crystallographic phases of [Zn1-xFex(ptz)(6)](BF4)(2) single crystals (x = 0.1, 0.23, and 1; ptz = 1-n-propyltetrazole) [J].
Jeftic, J ;
Hauser, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (49) :10262-10270
[10]   Spin-transition polymers: From molecular materials toward memory devices [J].
Kahn, O ;
Martinez, CJ .
SCIENCE, 1998, 279 (5347) :44-48