Aerocellulose: Aerogels and aerogel-like materials made from cellulose

被引:153
作者
Innerlohinger, Josef [1 ]
Weber, Hedda K. [1 ]
Kraft, Gregor [1 ]
机构
[1] Lenzing AG, A-4860 Lenzing, Austria
关键词
aerogels; biomaterials; cellulose; microstructure; N-methyl-morpholine-N-oxide (NMMO);
D O I
10.1002/masy.200651212
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Cellulose aerogels have been prepared starting from cellulose-NMMO solutions via the classical aerogel-path. Different cellulosic materials have been tested and their influence on the properties of the product aerogels has been studied. other parameters that have been varied include solution composition as well as the way of cellulose regeneration (solvent and temperature). More than 300 different samples were prepared and analysed. Their density is in a typical range from 0.02 g/cm(2) to 0.2 g/cm(3) and their internal surface area ranges from 100 m(2)/g to 400 m(2)/g. Another property investigated in detail beside density and internal surface area was the shrinkage of the cellulosic bodies during the production process.
引用
收藏
页码:126 / 135
页数:10
相关论文
共 31 条
[1]   Structure analysis of regenerated cellulose hydrogels by small-angle and ultra-small-angle x-ray scattering [J].
Ando, H ;
Konishi, T .
PHYSICAL REVIEW E, 2000, 62 (01) :727-733
[2]  
ARMSTRONG RN, 1980, K INT DISS PULPS C A
[3]   THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].
BARRETT, EP ;
JOYNER, LG ;
HALENDA, PP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380
[4]   Structural Investigation of Resorcinol Formaldehyde and Carbon Aerogels Using SAXS and BET [J].
Bock, V. ;
Emmerling, A. ;
Saliger, R. ;
Fricke, J. .
JOURNAL OF POROUS MATERIALS, 1997, 4 (04) :287-294
[5]   Adsorption of gases in multimolecular layers [J].
Brunauer, S ;
Emmett, PH ;
Teller, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319
[6]   Cellulose-based aerogels [J].
Fischer, F. ;
Rigacci, A. ;
Pirard, R. ;
Berthon-Fabry, S. ;
Achard, P. .
POLYMER, 2006, 47 (22) :7636-7645
[7]  
FISCHER F, 2005, 7 EUR S EL ENG TOUL
[8]   All-cellulose nanocomposite [J].
Gindl, W ;
Keckes, J .
POLYMER, 2005, 46 (23) :10221-10225
[9]  
HEINZE T, 2005, TECNOLOGIA, V15, P84
[10]  
Innerlohinger J., 2006, LENZINGER BERICHTE, V86, P137