The Determination of Methylmercury in Real Samples Using Organically Capped Mesoporous Inorganic Materials Capable of Signal Amplification

被引：109

作者：

Climent, Estela ^{[1
]}

Dolores Marcos, M. ^{[1
]}

Martinez-Manez, Ramon ^{[1
]}

Sancenon, Felix ^{[1
]}

Soto, Juan ^{[1
]}

Rurack, Knut ^{[2
]}

Amoros, Pedro ^{[3
]}

机构：

[1] Univ Politecn Valencia, Inst Reconocimiento Mol & Desarrollo Tecnol, Ctr Mixto, Univ Valencia,Dept Quim, Valencia 46022, Spain

[2] BAM Bundesanstalt Mat Forsch & Prufung, Div 15, D-12489 Berlin, Germany

[3] Univ Valencia, Inst Ciencia Mat ICMUV, Valencia 46071, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 45期

关键词：

chemosensors; fluorescence; mesoporous materials; methylmercury; MICROWAVE-ASSISTED EXTRACTION; ON FLUORESCENT SENSOR; INDUCED DYE FORMATION; AQUEOUS-MEDIA; SUPRAMOLECULAR CHEMISTRY; LIQUID-CHROMATOGRAPHY; CONTROLLED-RELEASE; HYBRID MATERIALS; TOTAL MERCURY; FISH-TISSUES;

D O I：

10.1002/anie.200904243

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The affinity of methylmercury towards capping leuko-squaraine groups (see picture, white) induces the opening of the pores of a capped mesoporous hybrid material and the release of entrapped safranine dyes (orange), thus allowing the selective optical detection of methylmercury in complex biological samples. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8519 / 8522

页数：4

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