Catalytic combustion of volatile organic compounds in binary mixtures over MnOx/Al2O3 catalyst

被引：110

作者：

Aguero, Fabiola N. ^{[1
]}

Barbero, Bibiana P. ^{[1
]}

Gambaro, Luis ^{[2
]}

Cadus, Luis E. ^{[1
]}

机构：

[1] UNSL CONICET, Inst Invest Tecnol Quim INTEQUI, RA-5700 San Luis, Argentina

[2] UNLP, CONICET, CINDECA, Fac Ciencias Exactas, La Plata, Buenos Aires, Argentina

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2009年 / 91卷 / 1-2期

关键词：

Alumina; Manganese oxide; VOC mixtures; Total oxidation; VOC MIXTURES; OXIDATION; ETHANOL; OXIDES; DESTRUCTION; MANGANESE; CHEMISTRY; PLATINUM;

D O I：

10.1016/j.apcatb.2009.05.012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this work the catalytic performance of an alumina supported manganese oxide catalyst in ethanol, ethyl acetate, toluene and mixtures of them was studied. The reactivity of each VOC investigated increased in the following order: ethanol > ethyl acetate > toluene. Toluene affects acetaldehyde yields, favoring partial combustion of ethanol and ethyl acetate. There is a competition for the adsorption sites between ethanol and ethyl acetate because both are polar molecules. Mixture effect decreases when the conversion temperature range of each component in the mixture is different, as in the case of ethanol-toluene and ethyl acetate-toluene mixture, consequently, the total conversion temperature is determined by the temperature at which the most difficult molecule is oxidized, in this case toluene. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：108 / 112

页数：5

共 18 条

[1] Combustion of volatile organic compounds over supported manganese oxide:: Influence of the support, the precursor and the manganese loading [J].

Aguero, Fabiola N. ;

Scian, Alberto ;

Barbero, Bibiana P. ;

Cadus, Luis E. .

CATALYSIS TODAY, 2008, 133 :493-501

[2] Atmospheric chemistry of VOCs and NOx [J].

Atkinson, R .

ATMOSPHERIC ENVIRONMENT, 2000, 34 (12-14) :2063-2101

[3] Catalytic combustion of methane in the presence of organic and inorganic compounds over La0.9Ce0.1CoO3 catalyst [J].

Auer, R ;

Alifanti, M ;

Delmon, B ;

Thyrion, FC .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 39 (04) :311-318

[4] MIXTURE EFFECTS IN DEEP CATALYTIC-OXIDATION OF ETHANOL OVER PLATINUM - INFLUENCE OF BENZENE AND ETHENYLBENZENE ON RATE AND SELECTIVITY [J].

BARRESI, AA ;

BALDI, G .

CHEMICAL ENGINEERING COMMUNICATIONS, 1993, 123 :31-42

[5] Deep oxidation of VOC mixtures with platinum supported on Al2O3/Al monoliths [J].

Burgos, N ;

Paulis, M ;

Antxustegi, MM ;

Montes, M .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 38 (04) :251-258

[6] Partial oxidation of ethanol over Pd/CeO2 and Pd/Y2O3 Catalysts [J].

Costa, L. O. O. ;

Silva, A. M. ;

Borges, L. E. P. ;

Mattos, L. V. ;

Noronha, F. B. .

CATALYSIS TODAY, 2008, 138 (3-4) :147-151

[7]

FINOCCHIO E, 1997, J CHEM SOC FARADAY T, V93, P75

[8] Combustion of aliphatic C2 chlorohydrocarbons over ceria-zirconia mixed oxides catalysts [J].

Gutiérrez-Ortiz, JI ;

de Rivas, B ;

López-Fonseca, R ;

González-Velasco, JR .

APPLIED CATALYSIS A-GENERAL, 2004, 269 (1-2) :147-155

[9] Evaluation of γ-MnO2 as a VOC removal catalyst:: Comparison with a noble metal catalyst [J].

Lahousse, C ;

Bernier, A ;

Grange, P ;

Delmon, B ;

Papaefthimiou, P ;

Ioannides, T ;

Verykios, X .

JOURNAL OF CATALYSIS, 1998, 178 (01) :214-225

[10] Oxides of copper, ceria promoted copper, manganese and copper manganese on Al2O3 for the combustion of CO, ethyl acetate and ethanol [J].

Larsson, PO ;

Andersson, A .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2000, 24 (3-4) :175-192

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