Ordered, nanostructured tin-based oxides/carbon composite as the negative-electrode material for lithium-ion batteries

被引:466
作者
Fan, J [1 ]
Wang, T [1 ]
Yu, CZ [1 ]
Tu, B [1 ]
Jiang, ZY [1 ]
Zhao, DY [1 ]
机构
[1] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Dept Chem, Shanghai 200433, Peoples R China
关键词
D O I
10.1002/adma.200400106
中图分类号
O6 [化学];
学科分类号
0703 [化学];
摘要
An ordered, nanostructured, tin-based oxides/carbon composite prepared by the full deposition of tin-based oxides into 3D nanospaces of mesoporous carbon is described. These novel nanostructured hybrid composites (see Figure) demonstrate a much better cycle performance as negative electrodes in lithium-ion batteries than nanosized tin-based oxides when cycled in a wide voltage range (0.02-2.0 V).
引用
收藏
页码:1432 / +
页数:6
相关论文
共 24 条
[1]
Influence of structure and composition upon performance of tin phosphate based negative electrodes for lithium batteries [J].
Behm, M ;
Irvine, JTS .
ELECTROCHIMICA ACTA, 2002, 47 (11) :1727-1738
[2]
Ordered nanoporous polymer-carbon composites [J].
Choi, M ;
Ryoo, R .
NATURE MATERIALS, 2003, 2 (07) :473-476
[3]
On the aggregation of tin in SnO composite glasses caused by the reversible reaction with lithium [J].
Courtney, IA ;
McKinnon, WR ;
Dahn, JR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (01) :59-68
[4]
Electrochemical and in situ x-ray diffraction studies of the reaction of lithium with tin oxide composites [J].
Courtney, IA ;
Dahn, JR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (06) :2045-2052
[5]
Key factors controlling the reversibility of the reaction of lithium with SnO2 and Sn2BPO6 glass [J].
Courtney, IA ;
Dahn, JR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (09) :2943-2948
[6]
Properties of containing Sn nanoparticles activated carbon fiber for a negative electrode in lithium batteries [J].
Egashira, M ;
Takatsuji, H ;
Okada, S ;
Yamaki, J .
JOURNAL OF POWER SOURCES, 2002, 107 (01) :56-60
[7]
Tin-based amorphous oxide: A high-capacity lithium-ion-storage material [J].
Idota, Y ;
Kubota, T ;
Matsufuji, A ;
Maekawa, Y ;
Miyasaka, T .
SCIENCE, 1997, 276 (5317) :1395-1397
[8]
Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure [J].
Jun, S ;
Joo, SH ;
Ryoo, R ;
Kruk, M ;
Jaroniec, M ;
Liu, Z ;
Ohsuna, T ;
Terasaki, O .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (43) :10712-10713
[9]
Reversible replication between ordered mesoporous silica and mesoporous carbon [J].
Kang, M ;
Yi, SH ;
Lee, HI ;
Yie, JE ;
Kim, JM .
CHEMICAL COMMUNICATIONS, 2002, (17) :1944-1945
[10]
Template synthesis of a new mesostructured silica from highly ordered mesoporous carbon molecular sieves [J].
Kim, JY ;
Yoon, SB ;
Yu, JS .
CHEMISTRY OF MATERIALS, 2003, 15 (10) :1932-1934