The oxidation of alkanes with dimethyldioxirane; A new mechanistic insight

被引：25

作者：

Asensio, G

Mello, R

GonzalezNunez, ME

Boix, C

Royo, J

机构：

[1] Depto. de Quimica Organica, Universidad de Valencia, 46100-Burjassot, Avda. V. A. Estellés s/n

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 13期

关键词：

OXYGEN-ATOM INSERTION; CARBON-HYDROGEN-BOND; CHROMYL CHLORIDE; METHYL(TRIFLUOROMETHYL)DIOXIRANE; DIOXIRANE; CHEMISTRY; OXYFUNCTIONALIZATION; HYDROCARBONS; ACTIVATION; RADICALS;

D O I：

10.1016/S0040-4039(97)00353-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Primary kinetic isotope effects were measured for the oxidation of cyclohexane and methylcyclohexane with DMDO in solution and in the gas phase. These experiments suggest an electrophilic oxygen insertion mechanism for the oxidation of alkanes by DMDO. (C) 1997 Published by Elsevier Science Ltd.

引用

页码：2373 / 2376

页数：4

共 20 条

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