An Energy Storage Principle using Bipolar Porous Polymeric Frameworks

被引：182

作者：

Sakaushi, Ken ^{[1
,2
]}

Nickerl, Georg ^{[2
]}

Wisser, Florian M. ^{[2
]}

Nishio-Hamane, Daisuke ^{[4
]}

Hosono, Eiji ^{[5
]}

Zhou, Haoshen ^{[5
]}

Kaskel, Stefan ^{[2
]}

Eckert, Juergen ^{[1
,3
]}

机构：

[1] IFW Dresden, Inst Complex Mat, D-01069 Dresden, Germany

[2] Tech Univ Dresden, Dept Inorgan Chem, Dresden, Germany

[3] Tech Univ Dresden, Inst Mat Sci, Dresden, Germany

[4] Univ Tokyo, ISSP, Tokyo 1138654, Japan

[5] Natl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tokyo, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 31期

关键词：

amorphous materials; bipolarity; energy storage; polymeric frameworks; porous materials; HIGH-POWER; ELECTRODE; CHALLENGES; BATTERIES; DESIGN;

D O I：

10.1002/anie.201202476

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Packed with energy: Amorphous covalent triazine-based frameworks were used as a cathode material, with the aim of developing an energy storage principle that can deliver a 2-3 times higher specific energy than current batteries with a high rate capability. The material undergoes a unique Faradaic reaction, as it can be present in both a p-doped and an n-doped state (see picture). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7850 / 7854

页数：5

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