Molecularly imprinted polymer film grafted from porous silica for selective recognition of testosterone

被引：29

作者：

He, CY ^{[1
]}

Liu, F ^{[1
]}

Li, KA ^{[1
]}

Liu, HW ^{[1
]}

机构：

[1] Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing 100871, Peoples R China

来源：

ANALYTICAL LETTERS | 2006年 / 39卷 / 02期

基金：

中国国家自然科学基金;

关键词：

surface grafting; molecularly imprinted polymer; porous silica; testosterone;

D O I：

10.1080/00032710500476946

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A type of testosterone-imprinted polymer film grafted from porous silica was prepared by covalently binding azo-initiators and then photo-grafting. Elemental analysis and infrared (IR) spectroscopy attested the polymer formation. The material could be polymerized within 10-60 min with reproducible grafting kinetics, controllable film thickness, and obviously specific recognition ability to testosterone with the imprinting factor of 1.52. Due to its uniform size, spherical shape, controllable film thickness, and accessible sites near or at the surface, this polymer could serve as a sensing element, solid-phase extraction material, or chromatographic stationary phase to selectively recognize or separate testosterone.

引用

页码：275 / 286

页数：12

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