The organic composition of air particulate matter from rural and urban Portuguese areas

被引:16
作者
Alves, C [1 ]
Pio, C
Duarte, A
机构
[1] Univ Aveiro, Dept Ambiente & Ordenamento, P-3810 Aveiro, Portugal
[2] Univ Aveiro, Dept Quim, P-3810 Aveiro, Portugal
来源
PHYSICS AND CHEMISTRY OF THE EARTH PART B-HYDROLOGY OCEANS AND ATMOSPHERE | 1999年 / 24卷 / 06期
关键词
D O I
10.1016/S1464-1909(99)00069-6
中图分类号
P4 [大气科学(气象学)];
学科分类号
0706 ; 070601 ;
摘要
Atmospheric particulate matter was simultaneously collected at three sites during an intensive campaign in August 1996. Two of the sampling sites were located in rural areas near or within forests. The third site was the University campus on the outskirts of the town of Aveiro. The collected aerosol was analysed in relation to black and organic carbon content. The particulate organic matter was extracted with solvents and characterised by Gas Chromatography and Mass Spectrometry (GC-MS). Most of the organic mass identified consists of alkanes, polycyclic aromatic hydrocarbons (PAH), ketones, aldehydes, alcohols and fatty acids both having a biogenic and anthropogenic origin. Photochemical products deriving from volatile organic compounds (VOC) emitted by vegetation represent an important fraction of the organic aerosol content. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:705 / 709
页数:5
相关论文
共 24 条
[1]  
ACEVES M, 1992, J CHROMATOGR A, V655, P133
[2]   Atmospheric aerosols: Biogeochemical sources and role in atmospheric chemistry [J].
Andreae, MO ;
Crutzen, PJ .
SCIENCE, 1997, 276 (5315) :1052-1058
[3]  
[Anonymous], 1996, ATMOS ENV, DOI DOI 10.1016/1352-2310(95)00336-3
[4]  
CHRISTOFFERSEN TS, ATMOS ENV, V31, P1657
[5]   Secondary organic aerosol from the photooxidation of aromatic hydrocarbons: Molecular composition [J].
Forstner, HJL ;
Flagan, RC ;
Seinfeld, JH .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1997, 31 (05) :1345-1358
[6]   Determination of organic molecular markers in marine aerosols and sediments: one-step flash chromatography compound class fractionation and capillary gas chromatographic analysis [J].
Gogou, AI ;
Apostolaki, M ;
Stephanou, EG .
JOURNAL OF CHROMATOGRAPHY A, 1998, 799 (1-2) :215-231
[7]   ATMOSPHERIC OXIDATION OF SELECTED TERPENES AND RELATED CARBONYLS - GAS-PHASE CARBONYL PRODUCTS [J].
GROSJEAN, D ;
WILLIAMS, EL ;
SEINFELD, JH .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1992, 26 (08) :1526-1533
[8]   PRODUCT FORMATION FROM THE GAS-PHASE REACTIONS OF OH RADICALS AND O3 WITH A SERIES OF MONOTERPENES [J].
HAKOLA, H ;
AREY, J ;
ASCHMANN, SM ;
ATKINSON, R .
JOURNAL OF ATMOSPHERIC CHEMISTRY, 1994, 18 (01) :75-102
[9]   REACTIONS OF OZONE WITH ALPHA-PINENE AND BETA-PINENE IN AIR - YIELDS OF GASEOUS AND PARTICULATE PRODUCTS [J].
HATAKEYAMA, S ;
IZUMI, K ;
FUKUYAMA, T ;
AKIMOTO, H .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1989, 94 (D10) :13013-13024
[10]   Formation of organic aerosols from the oxidation of biogenic hydrocarbons [J].
Hoffmann, T ;
Odum, JR ;
Bowman, F ;
Collins, D ;
Klockow, D ;
Flagan, RC ;
Seinfeld, JH .
JOURNAL OF ATMOSPHERIC CHEMISTRY, 1997, 26 (02) :189-222