Almost complete removal of trace amount of halogenated organic compounds in water: An approach by use of a combination of water-soluble thiacalixarene and ion-exchange resins
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作者:
Iki, N
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机构:Tohoku Univ, Dept Biomol Engn, Grad Sch Engn, Aoba Ku, Sendai, Miyagi 9808579, Japan
Iki, N
Fujimoto, T
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机构:Tohoku Univ, Dept Biomol Engn, Grad Sch Engn, Aoba Ku, Sendai, Miyagi 9808579, Japan
Fujimoto, T
Shindo, T
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机构:Tohoku Univ, Dept Biomol Engn, Grad Sch Engn, Aoba Ku, Sendai, Miyagi 9808579, Japan
Shindo, T
Koyama, K
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机构:Tohoku Univ, Dept Biomol Engn, Grad Sch Engn, Aoba Ku, Sendai, Miyagi 9808579, Japan
Koyama, K
Miyano, S
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机构:Tohoku Univ, Dept Biomol Engn, Grad Sch Engn, Aoba Ku, Sendai, Miyagi 9808579, Japan
Miyano, S
机构:
[1] Tohoku Univ, Dept Biomol Engn, Grad Sch Engn, Aoba Ku, Sendai, Miyagi 9808579, Japan
[2] Tohoku Univ, Environm Conservat Ctr, Aoba Ku, Sendai, Miyagi 9800845, Japan
Two removal methods of small halogenated organic substances in water are proposed by formation of ternary complexes between the halides, thiacalix[4]arenetetrasulfonate (TCAS), and anion exchange resins, among which treatment of the polluted water with TCAS to form TCAS-guest complexes followed by trapping them onto the resin enables almost complete (more than 99.99%) removal of halogenated organic compounds such as CH2Cl2 and CHCl3.