Polyaniline as an electrocatalytic material

被引：114

作者：

Mandic, Z

Duic, L

机构：

[1] University of Zagreb, Fac. of Chem. Eng. and Technology, Zagreb 41000

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1996年 / 403卷 / 1-2期

关键词：

polyaniline; electrocatalysis; location of reaction; counter-ion influence;

D O I：

10.1016/0022-0728(95)04358-6

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The catalytic influence of polyaniline (PANI) film, prepared from sulphuric and perchloric acid solutions, on hydroquinone/benzoquinone benzoquinone (HQ/BQ) and Fe-2+/3+ reactions has been investigated. The effect of the PANI layer thickness on redox reactions has been established, as well as different kinetics depending on the counter-ion incorporated. The location of the reactions taking place is discussed. Evidence is given for metal-like behaviour of PANI at potentials of emeraldine existence and redox-polymer behaviour at potentials of pernigraniline existence.

引用

页码：133 / 141

页数：9

共 41 条

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