A new synthetic method of 1,4-dihydro-2H-3,1-benzoxazin-2-ones:: Selenium-catalyzed reductive carbonylation of aromatic nitro compounds with carbon monoxide

被引：28

作者：

Nishiyama, Y ^{[1
]}

Naitoh, Y ^{[1
]}

Sonoda, N ^{[1
]}

机构：

[1] Kansai Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5648680, Japan

来源：

SYNLETT | 2004年 / 05期

关键词：

selenium; carbon monoxide; 1,4-dihydro-2H-3,1-benzoxazin-2-ones; carbonylation; carbamates;

D O I：

10.1055/s-2004-820018

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It was confirmed that selenium catalyzed the reaction of 2-nitrobenzyl alcohols with carbon monoxide to afford 1,4-dihydro-2H-3,1-benzoxazin-2-ones in good yields. Similarly, seven-membered cyclic carbamate was prepared by the reaction of 2-(2-nitrophenyl)ethanol with carbon monoxide.

引用

页码：886 / 888

页数：3

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