Phenolic glycosides from Kaempferia parviflora

被引：50

作者：

Azuma, Toshiaki ^{[1
]}

Tanaka, Yasuo ^{[2
]}

Kikuzaki, Hiroe ^{[1
]}

机构：

[1] Osaka City Univ, Grad Sch Human Life Sci, Div Food & Hlth Sci, Sumiyoshi Ku, Osaka 558, Japan

[2] Taiyo Corp, Osaka, Japan

来源：

PHYTOCHEMISTRY | 2008年 / 69卷 / 15期

关键词：

Kaempferia parviflora; Zingiberaceae; Phenolic glycoside;

D O I：

10.1016/j.phytochem.2008.09.001

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Three phenolic glycosides were isolated together with two known flavonol glycosides from the H2O-soluble fraction of rhizomes of Kaempferia parviflora. Their structures were determined to be rel-(5aS,10bS)-5a,10b-dihydro-1,3,5a,9-tetrahydroxy-8-methoxy-6H-benz[b]indeno[1,2-d]furan-6-one 5a-O-[alpha-L-rhamnopyranosyl-(1 -> 6)-beta-D-glucopyranoside] (1), its rel-5aS,10bR isomer (2), and (2R,3S,4S)-3-O-[alpha-L-rhamnopyranosyl-(1 -> 6)-beta-D-glucopyranosyl]-3'-O-methyl-ent-epicatechin-(2 alpha -> O -> 3,4 alpha -> 4)-(5aS, 10bS)-5a, 10b-dihydro-1,3,5a,9-tetrahydroxy-8-methoxy-6H-benz[b]indeno[1,2-d]furan-6-one 5a-O-[alpha-L-rhamnopyranosyl-(1 -> 6)-beta-D-glucopyranoside] (3). The structures were elucidated on the basis of analyses of chemical and spectroscopic evidence. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：2743 / 2748

页数：6

共 38 条

[1] PLANTS OF NEW-CALEDONIA .105. BUBBIALINE AND BUBBIALIDINE, NEW ALKALOIDS EXTRACTED FROM ZYGOGYNUM-PAUCIFLORUM [J].

AHOND, A ;

GUILHEM, J ;

HAMON, J ;

HURTADO, J ;

POUPAT, C ;

PUSSET, J ;

PUSSET, M ;

SEVENET, T ;

POTIER, P .

JOURNAL OF NATURAL PRODUCTS, 1990, 53 (04) :875-881

[2] Terpenoids and a diarylheptanoid from Zingiber ottensii [J].

Akiyama, Kayo ;

Kikuzaki, Hiroe ;

Aoki, Takako ;

Okuda, Akiko ;

Lajis, Nordin H. ;

Nakatani, Nobuji .

JOURNAL OF NATURAL PRODUCTS, 2006, 69 (11) :1637-1640

[3] CHEMICAL CONSTITUENTS OF ALNUS-SIEBOLDIANA (BETULACEAE) .2. ISOLATION AND STRUCTURE OF FLAVONOIDS AND STILBENES [J].

ASAKAWA, Y .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1971, 44 (10) :2761-+

[4] PLANT PROANTHOCYANIDINS .6. CHIROPTICAL STUDIES .95. CIRCULAR-DICHROISM OF PROCYANIDINS [J].

BARRETT, MW ;

KLYNE, W ;

SCOPES, PM ;

FLETCHER, AC ;

PORTER, LJ ;

HASLAM, E .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1979, (10) :2375-2377

[5] Flavonol glycosides from Eschscholtzia californica [J].

Beck, MA ;

Häberlein, H .

PHYTOCHEMISTRY, 1999, 50 (02) :329-332

[6] 3 FLAVANONES FROM LEAVES OF EUCALYPTUS-SIEBERI [J].

BICK, IRC ;

BROWN, RB ;

HILLIS, WE .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1972, 25 (02) :449-&

[7] Eicosenones and methylated flavonols from Amomum koenigii [J].

Dong, H ;

Gou, YL ;

Cao, SG ;

Chen, SX ;

Sim, KY ;

Goh, SH ;

Kini, RM .

PHYTOCHEMISTRY, 1999, 50 (05) :899-902

[8] New compounds obtained by evolution and oxidation of malvidin 3-O-glucoside in ethanolic medium [J].

Es-Safi, Nour-Eddine ;

Meudec, Emmanuelle ;

Bouchut, Claire ;

Fulcrand, Helene ;

Ducrot, Paul-Henri ;

Herbette, Gaeetan ;

Cheynier, Veronique .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2008, 56 (12) :4584-4591

[9] C-13 SUBSTITUENT EFFECTS IN MONOSUBSTITUTED BENZENES [J].

EWING, DF .

ORGANIC MAGNETIC RESONANCE, 1979, 12 (09) :499-524

[10] FLAVONOIDS FROM SALVIA-TEXANA [J].

GONZALEZ, AG ;

AGUIAR, ZE ;

LUIS, JG ;

RAVELO, AG ;

VAZQUEZ, JT ;

DOMINGUEZ, XA .

PHYTOCHEMISTRY, 1989, 28 (10) :2871-2872

← 1 2 3 4 →