Metal selection of ligand functionality in [(mes)(2)P(-O)(2)Li center dot 2thf](2) and [{(Me(3)Si)(2)N}Cd{(mes)(2)P-O}Li-2 center dot 2thf](mes equals C(6)H(2)Me(3)-2,4,6)

被引：27

作者：

Beswick, MA ^{[1
]}

Cromhout, NL ^{[1
]}

Harmer, CN ^{[1
]}

Palmer, JS ^{[1
]}

Raithby, PR ^{[1
]}

Steiner, A ^{[1
]}

Verhorevoort, KL ^{[1
]}

Wright, DS ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,DEPT CHEM,CAMBRIDGE CB2 1EW,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 06期

关键词：

D O I：

10.1039/a608202e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of LiBu(n) with [(mes)(2)P(H)=O] affords the diorganophosphinate complex [(mes)(2)P(O)(2)Li . 2thf] 1 and [(mes)(2)PLi], however, addition of [Cd{N(SiMe(3))(2)}(2)] to the mixture gives the diorganophosphinite complex [{Me(3)-Si)(2)N}Cd{(mes)(2)PO}(2)Li . 2thf] 2; the formation of these complexes illustrates that the ligand functionality of 1 can be controlled by the character of the coordinated metal ion.

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页码：583 / 584

页数：2

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