Ferroelectric fatigue of Pb(Zr,Ti)O3 thin films measured in atmospheres of varying oxygen concentration

被引:65
作者
Brazier, M [1 ]
Mansour, S [1 ]
McElfresh, M [1 ]
机构
[1] Purdue Univ, W Lafayette, IN 47907 USA
关键词
D O I
10.1063/1.123251
中图分类号
O59 [应用物理学];
学科分类号
摘要
Ferroelectric fatigue in Pb(Zr,Ti)O-3 films was found to be remarkably sensitive to the oxygen partial pressure of the atmosphere above the film during measurement. Films with Zr/Ti ratios of 55/45 and 75/25 were subjected to ferroelectric fatigue testing at room temperature in atmospheres of various oxygen partial pressure, or pO(2). The number of switching cycles at which the onset of fatigue occurred was found to be sharply peaked with respect to the oxygen partial pressure surrounding the sample. Such a striking dependence on the oxygen concentration strongly supports current theories for fatigue that involve oxygen vacancy migration. (C) 1999 American Institute of Physics. [S0003-6951(99)00726-3].
引用
收藏
页码:4032 / 4033
页数:2
相关论文
共 15 条
[1]   Unconventional hysteresis behavior in compositionally graded Pb(Zr,Ti)O3 thin films [J].
Brazier, M ;
McElfresh, M ;
Mansour, S .
APPLIED PHYSICS LETTERS, 1998, 72 (09) :1121-+
[2]  
BRAZIER M, UNPUB
[3]  
BRAZIER M, 1995, MATER RES SOC S P, V541, P507
[4]   TEMPERATURE DEPENDENT FATIGUE RATES IN THIN-FILM FERROELECTRIC CAPACITORS [J].
Brennan, Ciaran J. ;
Parrella, Ronald D. ;
Larsen, Duane E. .
FERROELECTRICS, 1994, 151 (01) :33-38
[5]   PULSED-LASER ABLATION SYNTHESIS AND CHARACTERIZATION OF LAYERED PT/SRBI2TA2O9/PT FERROELECTRIC CAPACITORS WITH PRACTICALLY NO POLARIZATION FATIGUE [J].
DAT, R ;
LEE, JK ;
AUCIELLO, O ;
KINGON, AI .
APPLIED PHYSICS LETTERS, 1995, 67 (04) :572-574
[6]   GRAIN-SIZE EFFECTS IN FERROELECTRIC SWITCHING [J].
DUIKER, HM ;
BEALE, PD .
PHYSICAL REVIEW B, 1990, 41 (01) :490-495
[7]   Superoxidation and electrochemical reactions during switching in Pb(Zr,Ti)O-3 ceramics [J].
Pan, MJ ;
Park, SE ;
Park, CW ;
Markowski, KA ;
Yoshikawa, S ;
Randall, CA .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1996, 79 (11) :2971-2974
[8]  
PFEFFER RL, 1995, MATER RES SOC SYMP P, V361, P117
[9]   FERROELECTRIC MEMORIES [J].
SCOTT, JF ;
DEARAUJO, CAP .
SCIENCE, 1989, 246 (4936) :1400-1405
[10]   QUANTITATIVE MEASUREMENT OF SPACE-CHARGE EFFECTS IN LEAD ZIRCONATE-TITANATE MEMORIES [J].
SCOTT, JF ;
ARAUJO, CA ;
MELNICK, BM ;
MCMILLAN, LD ;
ZULEEG, R .
JOURNAL OF APPLIED PHYSICS, 1991, 70 (01) :382-388