[Re(NBH2SBH3)(Me2PhP)(Et2dtc)]2 -: a novel rhenium dimer with the unusual bridging (NBH2SBH3)4- ligand

被引：9

作者：

Abram, U ^{[1
]}

机构：

[1] Dresden Univ Technol, Inst Analyt Chem, Forschungszentrum Rossendorf, Inst Radiochem, D-01062 Dresden, Germany

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 06期

关键词：

rhenium complexes; nitrido bridge complexes; diborinyl sulfide complexes; crystal structures;

D O I：

10.1016/S1387-7003(99)00054-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound is formed during the reaction of [ReN(Me2PhP) (Et(2)dtc)(2)] (Me2PhP = dimethylphenylphosphine, Et(2)dtc(-) = diethyldithiocarbamate) with excess BH3 in tetrahydrofurane. Two Re-v atoms are linked by two (NBH2SBH3)(4-) units which act as three-dentate ligands via N, S and H forming an eight-membered metallacycle with additional coordination of an hydride H atom trans to the nitrogen atom. The ReN multiple bond length is 1.70(1) Angstrom which is only slightly longer than in the starting compound [ReN(Me2PhP) (Et(2)dtc)(2)] (1.666(6) Angstrom). (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：227 / 229

页数：3

共 14 条

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