An air-stable, primary alkylphosphine: FcCH(2)PH(2) [Fc=(eta(5)-C5H5)Fe(eta(5)-C5H4)]

被引：43

作者：

Goodwin, NJ ^{[1
]}

Henderson, W ^{[1
]}

Nicholson, BK ^{[1
]}

机构：

[1] UNIV WAIKATO,DEPT CHEM,HAMILTON,NEW ZEALAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 01期

关键词：

D O I：

10.1039/a606580e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sodium metabisulfite-mediated elimination of formaldehyde from the ferrocene-derived hydroxymethylphosphine FcCH(2)P(CH2OH)(2) yields the primary phosphine FcCH(2)PH(2), which has been fully characterised, including an X-ray crystal structure; the phosphine is completely air-stable.

引用

收藏

页码：31 / 32

页数：2

相关论文

共 24 条

[1] SUCCESSFUL APPLICATION OF A FORGOTTEN PHOSPHINE IN ASYMMETRIC CATALYSIS - A 9-PHOSPHABICYCLO[3.3.1]NON-9-YL FERROCENE DERIVATIVE AS CHIRAL LIGAND [J].

ABBENHUIS, HCL ;

BURCKHARDT, U ;

GRAMLICH, V ;

KOLLNER, C ;

PREGOSIN, PS ;

SALZMANN, R ;

TOGNI, A .

ORGANOMETALLICS, 1995, 14 (02) :759-766

[2] THE DEVELOPMENT OF VERSION-3 AND VERSION-4 OF THE CAMBRIDGE STRUCTURAL DATABASE SYSTEM [J].

ALLEN, FH ;

DAVIES, JE ;

GALLOY, JJ ;

JOHNSON, O ;

KENNARD, O ;

MACRAE, CF ;

MITCHELL, EM ;

MITCHELL, GF ;

SMITH, JM ;

WATSON, DG .

JOURNAL OF CHEMICAL INFORMATION AND COMPUTER SCIENCES, 1991, 31 (02) :187-204

[3] A NEW CHIRAL TRIDENTATE FERROCENYL LIGAND - SYNTHESIS AND CHARACTERIZATION OF ITS PALLADIUM(II) AND NICKEL(II) COMPLEXES [J].

BARBARO, P ;

TOGNI, A .

ORGANOMETALLICS, 1995, 14 (07) :3570-3573

[4] ELECTRON DIFFRACTION STUDY OF MONOMETHYLPHOSPHINE AND DIMETHYLPHOSPHINE [J].

BARTELL, LS .

JOURNAL OF CHEMICAL PHYSICS, 1960, 32 (03) :832-834

[5] SYNTHESIS AND SPECTROSCOPIC AND X-RAY STRUCTURAL STUDIES OF THE MESITYLPHOSPHINES PH22,4,6-ME3C6H2 AND PH2,4,6-ME3C6H2 AND THEIR LITHIUM-SALTS [LI(THF)3PH2,4,6-ME3C6H2] AND [(LI(OET2)P2,4,6-ME3C6H22)2] [J].

BARTLETT, RA ;

OLMSTEAD, MM ;

POWER, PP ;

SIGEL, GA .

INORGANIC CHEMISTRY, 1987, 26 (12) :1941-1946

[6] WATER-SOLUBLE PHOSPHANES .3. WATER-SOLUBLE PRIMARY PHOSPHANES WITH AMMONIUM GROUPS NR(2)R' IN THE SIDE-CHAIN - DONOR-FUNCTIONALIZED AMPHIPHILES [J].

BRAUER, DJ ;

FISCHER, J ;

KUCKEN, S ;

LANGHANS, KP ;

STELZER, O ;

WEFERLING, N .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (11) :1511-1524

[7] THE PALLADIUM(II) COORDINATION CHEMISTRY OF FERROCENYLPHOSPHINOBIPYRIDINES - A NOVEL TRANS-CHELATING LIGAND SYSTEM [J].

BUTLER, IR ;

KALAJI, M ;

NEHRLICH, L ;

HURSTHOUSE, M ;

KARAULOV, AI ;

MALIK, KMA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (04) :459-460

[8] DIPHOSPHENES (RP=PR) - SYNTHESIS AND NMR CHARACTERIZATION [J].

COWLEY, AH ;

KILDUFF, JE ;

NEWMAN, TH ;

PAKULSKI, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (21) :5820-5821

[9]

DIXON KR, 1987, MULTINUCLEAR NMR

[10] MM3 MOLECULAR MECHANICS STUDY OF ALKYLPHOSPHINES [J].

FOX, PC ;

BOWEN, JP ;

ALLINGER, NL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (22) :8536-8544