Reaction of molecular oxygen with a PdII-hydride to produce a PdII-hydroperoxide:: Acid catalysis and implications for Pd-catalyzed aerobic oxidation reactions

被引：125

作者：

Konnick, Michael M. ^{[1
]}

Gandhi, Bhavesh A. ^{[1
]}

Guzei, Ilia A. ^{[1
]}

Stahl, Shannon S. ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 18期

关键词：

catalysis; molecular oxygen; oxidation; palladium;

D O I：

10.1002/anie.200600532

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A critical step: The reaction of molecular oxygen with a reduced palladium species represents the key step in Pd-catalyzed aerobic oxidation reactions. New PdII-hydride complexes 1 have been prepared which react with molecular oxygen to produce PdII- hydroperoxide adducts 2. Carboxylic acid catalysis of this reaction has important implications for Pd-catalyzed aerobic oxidation reactions. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2904 / 2907

页数：4

共 44 条

[1] Palladium complexes of 1,3,5,7-tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane:: Synthesis, crystal structure and use in the Suzuki and Sonogashira reactions and the α-arylation of ketones [J].