Novel ligands derived from S-tyrosine for the enantioselective addition of diethylzinc to aldehydes

被引:41
作者
Beliczey, J [1 ]
Giffels, G [1 ]
Kragl, U [1 ]
Wandrey, C [1 ]
机构
[1] FORSCHUNGSZENTRUM JULICH, FORSCHUNGSZENTRUM, INST BIOTECHNOL, D-52425 JULICH, GERMANY
关键词
D O I
10.1016/S0957-4166(97)00150-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
(S)-2-N,N-dibutylamino-3-butyl-1-[4-(4-phenylmethoxy)-phenyl]heptain-3-ol 3 based on (S)-tyrosine has been synthesised. For the diethylzinc addition to both aliphatic and aromatic aldehydes, high enantiomeric excesses up to 95% were obtained. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:1529 / 1530
页数:2
相关论文
共 10 条