Hydrogenography: An optical combinatorial method to find new light-weight hydrogen-storage materials

被引:189
作者
Gremaud, Robin
Broedersz, Chase P.
Borsa, Dana M.
Borgschulte, Andreas
Mauron, Philippe
Schreuders, Herman
Rector, Jan H.
Dam, Bernard
Griessen, Ronald
机构
[1] Vrije Univ Amsterdam, Dept Phys & Astron, NL-1081 HV Amsterdam, Netherlands
[2] EMPA, Dept Mobil Environm & Energy, Div 138, CH-8600 Dubendorf, Switzerland
关键词
D O I
10.1002/adma.200602560
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hydrogenography optically monitors hydrogen ab- and desorption simultaneously on thousands of alloy compositions under exactly the same experimental conditions. In this way the hydride-formation enthalpy map of the Mg-Ni-Ti-H system is determined from a compositional gradient thin film. The figure shows that the region of interesting hydrogen-storage materials is in dark blue, with enthalpies of around -40 kJ (mol H-2)(-1).
引用
收藏
页码:2813 / +
页数:6
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