The solvent promoted addition of tetraallyltin to aldehydes: A convenient and chemoselective allylation procedure

被引：29

作者：

Cokley, TM ^{[1
]}

Marshall, RL ^{[1
]}

McCluskey, A ^{[1
]}

Young, DJ ^{[1
]}

机构：

[1] GRIFFITH UNIV,FAC SCI & TECHNOL,NATHAN,QLD 4111,AUSTRALIA

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 11期

关键词：

D O I：

10.1016/0040-4039(96)00149-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aldehydes 2a - e react with tetraallyltin (1,0.25 equiv.) in methanol or other polar solvent at room temperature (ca 30 degrees C, <20 h) to provide the corresponding homoallyl alcohols 3a - e in 69 - 98% yield. No additional catalysis is required.

引用

页码：1905 / 1908

页数：4

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