Sila Morita-Baylis-Hillman reaction of cyclopropenes

被引:45
作者
Chuprakov, Stepan [1 ]
Malyshev, Denis A. [1 ]
Trofimov, Alexander [1 ]
Gevorgyan, Vladimir [1 ]
机构
[1] Univ Illinois, Dept Chem, Chicago, IL 60607 USA
关键词
D O I
10.1021/ja077437s
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first example of sila-Morita-Bayis-Hillman reaction between 1-silylcyclopropenes and carbonyl compounds has been demonstrated. This novel phosphine-catalyzed transformation features a 1,3-Brook rearrangement/elimination cascade and provides convenient access to a variety of 1-(silyloxymethyl)cyclopropenes, which are not easily available via traditional methods.
引用
收藏
页码:14868 / 14869
页数:2
相关论文
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