Organometallic reactions in aqueous media. Indium- and zinc-mediated allylation of sulfonimines

被引：107

作者：

Lu, WS ^{[1
]}

Chan, TH ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2000年 / 65卷 / 25期

关键词：

D O I：

10.1021/jo0009898

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sulfonimines derived from aryl and nonenolizable aliphatic aldehydes can be effectively allylated to the corresponding homoallylic sulfonamides with allylic bromides prompted by indium or zinc. The solvent used can be water, THF, or a mixed aqueous THF solvent. The regioselectivity and stereoselectivity of the reaction were studied.

引用

页码：8589 / 8594

页数：6

共 37 条

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[Anonymous], [No title captured]

[2]

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