The structure of the [Fe(CN)(6)](4-) shallow electron centre in silver chloride

被引：15

作者：

Bennebroek, MT ^{[1
]}

Schmidt, J ^{[1
]}

Eachus, RS ^{[1
]}

Olm, MT ^{[1
]}

机构：

[1] EASTMAN KODAK CO,IMAGING RES & ADV DEV,ROCHESTER,NY 14650

来源：

JOURNAL OF PHYSICS-CONDENSED MATTER | 1997年 / 9卷 / 15期

关键词：

D O I：

10.1088/0953-8984/9/15/014

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

The results of an ENDOR study of electrons shallowly trapped at [Fe(CN)(6)](4-) complexes doped in AgCl emulsions reveal that the dopant replaces a [AgCl6](5-) lattice unit without an additional lowering of the local symmetry and without the association of charge-compensating cationic vacancies. Effects of the grain structure seem to interfere in the interpretation of the results from C-13-enriched [Fe(CN)(6)](4-)-doped emulsions, for which an ensemble of slightly different electron centres is believed to be observed.

引用

页码：3227 / 3240

页数：14

共 22 条

[1]

[Anonymous], 1977, THEORY PHOTOGRAPHIC

[2]

BAETZOLD RC, 1997, IN PRESS J PHYS CHEM

[3]

BAETZOLD RC, 1996, INT C DEF INS MAT

[4]

BELL EL, 1992, Patent No. 5132203

[5] Spatial distribution of the wave function of the self-trapped exciton in AgCl [J].

Bennebroek, MT ;

Arnold, A ;

Poluektov, OG ;

Baranov, PG ;

Schmidt, J .

PHYSICAL REVIEW B, 1996, 53 (23) :15607-15616

[6] Shallow electron centers in silver halides [J].

Bennebroek, MT ;

Arnold, A ;

Poluektov, OG ;

Baranov, PG ;

Schmidt, J .

PHYSICAL REVIEW B, 1996, 54 (16) :11276-11289

[7] STRUCTURE OF THE INTRINSIC SHALLOW ELECTRON CENTER IN AGCL STUDIED BY PULSED ELECTRON-NUCLEAR DOUBLE-RESONANCE SPECTROSCOPY AT 95-GHZ [J].

BENNEBROEK, MT ;

POLUEKTOV, OG ;

ZAKRZEWSKI, AJ ;

BARANOV, PG ;

SCHMIDT, J .

PHYSICAL REVIEW LETTERS, 1995, 74 (03) :442-445

[8] THE CALCULATION OF DIPOLE-MOMENTS ASSOCIATED WITH DEFECTS IN IONIC-CRYSTALS [J].

CORISH, J ;

FITZSIMONS, PB ;

JACOBS, PWM .

PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 1987, 56 (01) :1-13

[9] A PULSED EPR AND ENDOR SPECTROMETER OPERATING AT 95 GHZ [J].

DISSELHORST, JAJM ;

VANDERMEER, H ;

POLUEKTOV, OG ;

SCHMIDT, J .

JOURNAL OF MAGNETIC RESONANCE SERIES A, 1995, 115 (02) :183-188

[10]

EACHUS RS, 1982, PHOTOGR SCI ENG, V26, P20

← 1 2 3 →