Rhodium-catalyzed coupling of sodium tetraphenylborate with acid anhydrides in the presence or absence of norbornene

被引：60

作者：

Oguma, K ^{[1
]}

Miura, M ^{[1
]}

Satoh, T ^{[1
]}

Nomura, M ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 648卷 / 1-2期

关键词：

rhodium catalyst; organoboron compounds; acid anhydrides; cross-coupling;

D O I：

10.1016/S0022-328X(01)01439-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of sodium tetraphenylborate with aliphatic or aromatic acid anhydrides in the presence of a rhodium catalyst gives the corresponding alkyl (or aryl) phenyl ketones in good yields. In the presence of norbornene, tandem three-component coupling products, 2-acyl-3-phenylnorbornanes are obtained. (C) 2002 Published by Elsevier Science B.V.

引用

页码：297 / 301

页数：5

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