The advanced carbide-derived carbon based supercapacitor

被引：188

作者：

Arulepp, M.

Leis, J.

Latt, M.

Miller, F.

Rumma, K.

Lust, E.

Burke, A. F.

机构：

[1] Tartu Technol Ltd, EE-51014 Tartu, Estonia

[2] Univ Tartu, EE-51014 Tartu, Estonia

[3] Estonian Maritime Acad, EE-13912 Tallinn, Estonia

[4] Univ Calif Davis, Davis, CA 95616 USA

来源：

JOURNAL OF POWER SOURCES | 2006年 / 162卷 / 02期

关键词：

carbide-derived carbon; nonaqueous electrolyte; electrical double-layer capacitor; Ragone plot;

D O I：

10.1016/j.jpowsour.2006.08.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electrical double-layer (EDL) performance of three different TiC-derived nanoporous carbon materials was tested in prismatic capacitor assembly filled with 1.2 M triethylmethylammonium tetrafluoroborate (TEMA) acetonitrile solution. The electrical double-layer characteristics of supercapacitors were studied using the cyclic voltammetry (CV) and the electrochemical impedance spectroscopy (EIS) methods. Energy density versus power density, i.e. Ragone plots were constructed from the constant resistance and constant power (CP) charge/discharge data. The 1450F supercapacitor with novel nanoporous carbon made by halogen treatment of eTiC/TiO2 composite demonstrated the energy density of more than 10 Wh dm(-3) at the cell voltage of 2.7 V. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：1460 / 1466

页数：7

共 24 条

[1] Influence of the solvent properties on the characteristics of a double layer capacitor
Arulepp, M
Permann, L
Leis, J
Perkson, A
Rumma, K
Jänes, A
Lust, E
[J]. JOURNAL OF POWER SOURCES, 2004, 133 (02) : 320 - 328
[2] ARULEPP M, 2003, THESIS CHEM U TARTUE, V38
[3] Capacitance limits of high surface area activated carbons for double layer capacitors
Barbieri, O
Hahn, M
Herzog, A
Kötz, R
[J]. CARBON, 2005, 43 (06) : 1303 - 1310
[4] Ultracapacitors: why, how, and where is the technology
Burke, A
[J]. JOURNAL OF POWER SOURCES, 2000, 91 (01) : 37 - 50
[5] Conway B. E., 1999, ELECTROCHEMICAL SUPE, DOI DOI 10.1007/978-1-4757-3058-6
[6] Nanoporous carbide-derived carbon with tunable pore size
Gogotsi, Y
Nikitin, A
Ye, HH
Zhou, W
Fischer, JE
Yi, B
Foley, HC
Barsoum, MW
[J]. NATURE MATERIALS, 2003, 2 (09) : 591 - 594
[7] JEROME A, 2005, 20050058875 US
[8] Hydrogen in carbon nanostructures
Johansson, E
Hjörvarsson, B
Ekström, T
Jacob, M
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 330 : 670 - 675
[9] Kurzweil P., 2005, P 15 INT SEM DOUBL L, P14
[10] Structural study of nanoporous carbon produced from polycrystalline carbide materials:: small-angle x-ray scattering
Kyutt, RN
Smorgonskaya, ÉA
Danishevskii, AM
Gordeev, SK
Grechinskaya, AV
[J]. PHYSICS OF THE SOLID STATE, 1999, 41 (08) : 1359 - 1363

← 1 2 3 →