Dipyrrin based luminescent cyclometallated palladium and platinum complexes

被引：82

作者：

Bronner, Catherine ^{[1
]}

Baudron, Stephane A. ^{[1
]}

Hosseini, Mir Wais ^{[1
]}

Strassert, Cristian A. ^{[2
,3
]}

Guenet, Aurelie ^{[2
]}

De Cola, Luisa ^{[2
]}

机构：

[1] Univ Strasbourg, Lab Chim Coordinat Organ, CNRS, UMR 7140, F-67000 Strasbourg, France

[2] Westfal Whilhems Univ Munster, Inst Phys, D-48149 Munster, Germany

[3] DPI, NL-5600 AX Eindhoven, Netherlands

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 01期

关键词：

METAL-ORGANIC FRAMEWORKS; COORDINATION; RUTHENIUM(II); ARCHITECTURES; PORPHYRINS; DYNAMICS;

D O I：

10.1039/b908424j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of complexes based on the combination of cyclometallated palladium or platinum moieties with functionalized dipyrrin ligands bearing mesityl- or benzonitrile groups have been prepared and characterized both in the solid state and in solution; these compounds exhibit a characteristic dipyrrin-centered luminescence with an emission intensity modulated by the degree of rotational freedom of the aromatic group attached to the dipyrrin chelate.

引用

页码：180 / 184

页数：5

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