Highly luminescent quantum-dot monoliths

被引:119
作者
Arachchige, Indika U. [1 ]
Brock, Stephanie L. [1 ]
机构
[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA
关键词
D O I
10.1021/ja066749c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Large (mm-cm) free-standing CdSe/ZnS core/shell quantum-dot networks (gels, xerogels, and aerogels) with high luminosity have been synthesized by oxidative removal of surface thiolate ligands from preformed core/shell particles. In contrast to analogous poorly emissive networks prepared from "naked" CdSe nanoparticles, the extent of quantum confinement in the 3-D connected solid is a function of the precursor particle size and shows little dependence on the network density.
引用
收藏
页码:1840 / +
页数:3
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