Construction of a rigid Zn Porphyrin-C60 dyad within dendritic structure:: Dendrimer effect on singlet energy transfer

被引：33

作者：

Kozaki, Masatoshi ^{[1
]}

Akita, Kogen ^{[1
]}

Suzuki, Shuichi ^{[1
]}

Okada, Keiji ^{[1
]}

机构：

[1] Osaka City Univ, Grad Sch Sci, Sumiyoshi Ku, Osaka 5588585, Japan

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 17期

关键词：

D O I：

10.1021/ol071296h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A snowflake-shaped Zn porphyrin dendrimer with a C-60 terminal was prepared. Covalent linkage of the C-60 unit results in significant quenching of the Zn porphyrin fluorescence mainly due to energy transfer from the Zn porphyrin core to the C-60 terminal. Comparison of the energy-transfer efficiency with similar dendrons indicates that the dendritic structure considerably delays the energy-transfer rate.

引用

页码：3315 / 3318

页数：4

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