Reaction of dodecacarbonyltriruthenium with cinnamaldehyde

被引：5

作者：

Rybinskaya, MI ^{[1
]}

Osintseva, SV ^{[1
]}

Rybin, LV ^{[1
]}

Dolgushin, FM ^{[1
]}

Yanovsky, AI ^{[1
]}

Petrovskii, PV ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117813, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1998年 / 47卷 / 05期

关键词：

dodecacarbonyltriruthenium; reaction with cinnamaldehyde; phenylvinylidene complex; X-ray diffraction analysis;

D O I：

10.1007/BF02498171

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of dodecacarbonyltriruthenium with cinnamaldehyde yielded a mixture of the known H4Ru4(CO)(12), H2Ru4(CO)(13), and H2Ru6(CO)(18), and Ru6C(CO)(17) clusters and the 1,1,1,2,2,2,3,3,3-nonacarbonyl- 1,2; 1,3 -(mu(2)-dihydrido)-1,3-sigma;2-pi-[mu(3) - eta(2)-(phenyl)vinylidene] triangulotriruthenium complex. The structure of the last-mentioned compound was established by X-ray diffraction study. The mechanism of the reaction and a possible pathway of formation of the vinylidene complex are discussed.

引用

页码：979 / 982

页数：4

共 16 条

[1] TRIOSMIUM CLUSTERS DERIVED FROM ALPHA,BETA-UNSATURATED ALDEHYDES [J].

ARCE, AJ ;

DESANCTIS, Y ;

DEEMING, AJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 295 (03) :365-369

[2]

BARNARD GFJ, 1979, J CHEM SOC DA, P1331

[3] SYNTHESIS OF NEW CARBOXYLATE- AND PHOSPHINATE-BRIDGED RUTHENIUM(I) DIMERS [J].

BOHLE, DS ;

VAHRENKAMP, H .

INORGANIC CHEMISTRY, 1990, 29 (05) :1097-1099

[4]

BOHLE DS, 1992, CHEM BER-RECL, V125, P1111

[5] CHEMISTRY OF POLYNUCLEAR COMPOUNDS .17. SOME CARBOXYLATE COMPLEXES OF RUTHENIUM AND OSMIUM CARBONYLS [J].

CROOKS, GR ;

JOHNSON, BFG ;

LEWIS, J ;

WILLIAMS, IG ;

GAMLEN, G .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (18) :2761-&

[6] REACTIONS OF ACETYLENE, METHYL-SUBSTITUTED AND PHENYL-SUBSTITUTED ACETYLENES, AND ETHYLENE WITH 1,1,1,1,2,2,2,3,3,3-DECACARBONYL-2,3-DI-MU-HYDRIDO-TRI-ANGULO-TRIOSMIUM [J].

DEEMING, AJ ;

HASSO, S ;

UNDERHILL, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (15) :1614-1620

[7] THE STRUCTURE OF 1,1,1,2,2,2,3,3,3-NONACARBONYL-1,2-1,3-(MU2-DIHYDRIDO)-1,3-SIGMA-2-PI-[MU3-ETA2-METHYL(PHENYL)VINYLIDENE]-TRIANGULO-TRIRUTHENIUM [J].

DODSWORTH, R ;

DUTTON, T ;

JOHNSON, BFG ;

LEWIS, J ;

RAITHBY, PR .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 :707-710

[8] IMPROVED SYNTHESES OF THE HEXANUCLEAR CLUSTERS [RU6(CO)18]2-, [HRU6-(CO)18]-, AND H2RU6(CO)18 - X-RAY-ANALYSIS OF [HRU6(CO)18]-, - POLYNUCLEAR CARBONYL CONTAINING AN INTERSTITIAL HYDROGEN LIGAND [J].

EADY, CR ;

JACKSON, PF ;

JOHNSON, BFG ;

LEWIS, J ;

MALATESTA, MC ;

MCPARTLIN, M ;

NELSON, WJH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (03) :383-392

[9] REACTIONS OF COORDINATED LIGANDS .46. FORMATION OF [OS3(MU-H)(MU-CCH2CHME2)(CO)10] AND [OS3(MU-H)(MU-CCH=CME2)(CO)10] BY CARBON CARBON SIGMA-BOND AND CARBON HYDROGEN ACTIVATION OF 3,3-DIMETHYLCYCLOPROPENE - CRYSTAL AND MOLECULAR-STRUCTURE OF [OS3(MU-H)(MU-CCH2CHME2)(CO)10] AND EVIDENCE FOR ITS FACILE REARRANGEMENT TO [OS3(MU-H)(MU-CH=CHCHME2)(CO)10]3 [J].

GREEN, M ;

ORPEN, AG ;

SCHAVERIEN, CJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (07) :1333-1340

[10] REACTIVITY OF DERIVATIVES OF PHOSPHORUS YLIDES ON RU3 CLUSTERS - INTERCONVERSIONS DUE TO ALKYNE INSERTION [J].

HEINEKE, D ;

VAHRENKAMP, H .

CHEMISCHE BERICHTE-RECUEIL, 1993, 126 (02) :365-371

← 1 2 →