A new synthesis of bis(2-{pyrid-2-yl}ethyl)amine (LH) from bis(2-{pyrid-2-yl}ethyl)hydroxylamine (LOH), and the copper-dependent reduction of LOH to LH

被引：19

作者：

Leaver, SA

Palaniandavar, M

Kilner, CA

Halcrow, MA

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

[2] Bharathidasan Univ, Dept Chem, Tiruchirappalli 620024, India

来源：

DALTON TRANSACTIONS | 2003年 / 22期

关键词：

D O I：

10.1039/b310144d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solutions of [CuCl2LOH], and other reaction mixtures containing L-OH and Cu(II) or Cu(I) salts, degrade to yield dark green or brown residues containing the L-H ligand. In contrast, [MCl2LOH] (M = Zn, Ni, Co) are indefinitely stable in solution and the solid state.

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页码：4224 / 4225

页数：2

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