Physical properties of conducting polymer nanofibers

被引：23

作者：

Duvail, JL

Rétho, P

Godon, C

Marhic, C

Louarn, G

Chauvet, O

Cuenot, S

Pra, NLDD

Demoustier-Champagne, S

机构：

[1] LPC, Inst Mat Nantes, F-44072 Nantes 03, France

[2] Univ Catholique Louvain, POLY, B-1348 Louvain, Belgium

来源：

SYNTHETIC METALS | 2003年 / 135卷 / 1-3期

关键词：

nanotube; polypyrrole and derivatives; polythiophene and derivatives; transport measurements; metal-insulator phase transitions;

D O I：

10.1016/S0379-6779(02)00626-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Nanofibers of poly(3,4-ethylenedioxythiophene) - PEDOT and polypyrrole - PPy have been prepared using the template method. We present a study of the electronic and mechanical properties of these nanofibers. Strong variations of the estimated conductivity, the resistivity ratio rho(1.5K)/rho(300K) and the elastic modulus are observed when the diameter is reduced from 200nm to 20nm. They are discussed in terms of change in the conformation of the polymer chains and/or doping level due to the confinement.

引用

收藏

页码：329 / 330

页数：2

相关论文

共 10 条

[1] Elastic modulus of polypyrrole nanotubes [J].

Cuenot, S ;

Demoustier-Champagne, S ;

Nysten, B .

PHYSICAL REVIEW LETTERS, 2000, 85 (08) :1690-1693

[2] Effect of electrolyte concentration and nature on the morphology and the electrical properties of electropolymerized polypyrrole nanotubules [J].

Demoustier-Champagne, S ;

Stavaux, PY .

CHEMISTRY OF MATERIALS, 1999, 11 (03) :829-834

[3] Chemical synthesis of polypyrrole: structure-properties relationship [J].

Duchet, J ;

Legras, R ;

Demoustier-Champagne, S .

SYNTHETIC METALS, 1998, 98 (02) :113-122

[4]

DUVAIL JL, 2002, UNPUB SYNTH MET

[5] Characterisation of nanoporous particle track etched membrane [J].

Ferain, E ;

Legras, R .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1997, 131 (1-4) :97-102

[6] ELECTRICALLY CONDUCTIVE POLYMER FIBERS WITH MESOSCOPIC DIAMETERS .1. STUDIES OF STRUCTURE AND ELECTRICAL-PROPERTIES [J].

GRANSTROM, M ;

INGANAS, O .

POLYMER, 1995, 36 (15) :2867-2872

[7]

HANOT H, 2001, Patent No. 00149403

[8] NANOMATERIALS - A MEMBRANE-BASED SYNTHETIC APPROACH [J].

MARTIN, CR .

SCIENCE, 1994, 266 (5193) :1961-1966

[9] Investigation of molecular and supermolecular structure in template-synthesized polypyrrole tubules and fibrils [J].

Menon, VP ;

Lei, JT ;

Martin, CR .

CHEMISTRY OF MATERIALS, 1996, 8 (09) :2382-2390

[10] Anionic micelles; A new aqueous medium for electropolymerization of poly(3,4-ethylenedioxythiophene) films on Pt electrodes [J].

Sakmeche, N ;

Aaron, JJ ;

Fall, M ;

Aeiyach, S ;

Jouini, M ;

Lacroix, JC ;

Lacaze, PC .

CHEMICAL COMMUNICATIONS, 1996, (24) :2723-2724