The first synthesis of the ketene dithioacetals from sugar lactones: a convenient access to 3-ulosonic acids

被引：11

作者：

Mlynarski, J ^{[1
]}

Banaszek, A ^{[1
]}

机构：

[1] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 30期

关键词：

homologation; ketene; thioacetals; lactones;

D O I：

10.1016/S0040-4039(98)01045-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Isomeric 2-deoxy aldonolactones undergo Horner-Emmons reactions with 2-[bis(2,2,2-trifluoroethoxy)phosphoryl]1,3-dithiane, to give the corresponding ketene dithioacetals, which are the key intermediates in the synthesis of 3-deoxy-2-keto-aldonic acids. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：5425 / 5428

页数：4

共 23 条

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