Polymer-supported titanates as catalysts for transesterification reactions

被引：61

作者：

Deleuze, H

Schultze, X

Sherrington, DC

机构：

[1] Univ Bordeaux 1, Chim Organ & Organomet Lab, CNRS, UMR 5802, F-33405 Talence, France

[2] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

来源：

POLYMER | 1998年 / 39卷 / 24期

关键词：

organometallic transesterification catalysts; polymer-supported titanates; methyl methacrylate;

D O I：

10.1016/S0032-3861(98)00080-9

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polymer-supported titanates were prepared by covalent bonding of a trialkoxychlorotitane to a preformed macroporous poly(4-hydroxystyrene) resin. The reactivity and stability to recycling of the catalyst obtained were demonstrated in the catalysis of the transesterifications of methyl methacrylate with 2-ethylhexanol and ethyl butyrate with 1-dodecanol. A low leaching of titanium was observed during four successive uses of the resin as a transesterification catalyst. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：6109 / 6114

页数：6

共 16 条

[1] PHENOLIC RESINS FOR SOLID-PHASE PEPTIDE-SYNTHESIS - COPOLYMERIZATION OF STYRENE AND PARA-ACETOXYSTYRENE
ARSHADY, R
KENNER, GW
LEDWITH, A
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1974, 12 (09) : 2017 - 2025
[2] Homogeneous and supported titanates as catalysts for transesterification of acrylic esters
Blandy, C
Pellegatta, JL
Cassoux, P
[J]. CATALYSIS LETTERS, 1997, 43 (1-2) : 139 - 142
[3] CATALYTIC PROPERTIES OF SUPPORTED TITANATES IN TRANSESTERIFICATION
BLANDY, C
PELLEGATTA, JL
GILOT, B
[J]. JOURNAL OF CATALYSIS, 1994, 150 (01) : 150 - 154
[4] TOXICITY OF DIBUTYLTIN, TRIBUTYLTIN AND OTHER ORGANOTIN COMPOUNDS TO HUMANS AND TO EXPERIMENTAL-ANIMALS
BOYER, IJ
[J]. TOXICOLOGY, 1989, 55 (03) : 253 - 298
[5] POLY(P-ACETOXYSTYRENE) RESIN - A PROSPECTIVE NEW SUPPORT FOR COMBINATORIAL SYNTHESIS
DELEUZE, H
SHERRINGTON, DC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1995, (12): : 2217 - 2221
[6] TRANSESTERIFICATION REACTIONS IN MOLTEN POLYMERS
LAMBLA, M
DRUZ, J
BOUILLOUX, A
[J]. POLYMER ENGINEERING AND SCIENCE, 1987, 27 (16) : 1221 - 1228
[7] ASYMMETRIC GLYOXYLATE ENE REACTION CATALYZED BY CHIRAL TITANIUM COMPLEXES - A PRACTICAL ACCESS TO ALPHA-HYDROXY ESTERS IN HIGH ENANTIOMERIC PURITIES
MIKAMI, K
TERADA, M
NAKAI, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (05) : 1940 - 1941
[8] Pesneau I, 1997, J APPL POLYM SCI, V65, P2457, DOI 10.1002/(SICI)1097-4628(19970919)65:12<2457::AID-APP17>3.0.CO
[9] 2-Y
[10] SEEBACH D, 1982, SYNTHESIS-STUTTGART, P138

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