Effect of metal clusters on the swelling of gold-fluorocarbon-polymer composite films

被引:22
作者
Convertino, A
Valentini, A
Bassi, A
Cioffi, N
Torsi, L
Cirillo, ENM
机构
[1] CNR, Ist Chim Mat, Area Ric Roma, I-00016 Monterotondo, Italy
[2] Univ Bari, Ist Nazl Fis Mat, Dipartimento Fis, I-70126 Bari, Italy
[3] Univ Bari, Dipartmento Chim, I-70126 Bari, Italy
[4] Univ Roma La Sapienza, Dipartimento Me Mo Mat, I-00161 Rome, Italy
关键词
D O I
10.1063/1.1448858
中图分类号
O59 [应用物理学];
学科分类号
摘要
We have investigated the swelling of acetone in fluorocarbon polymer films doped with different gold concentrations below the percolation threshold. The presence of the gold clusters in the polymer improves the mixing between the polymer and the acetone, which is not a good solvent for this kind of polymer. To explain our results, the stoichiometry and the morphology of the polymer-metal system have been studied and a modified Flory-Huggins model has been developed. (C) 2002 American Institute of Physics.
引用
收藏
页码:1565 / 1567
页数:3
相关论文
共 14 条
[1]  
[Anonymous], 1981, INTRO POLYM
[2]   Dielectric and microstructure properties of polymer carbon black composites [J].
Brosseau, C ;
Boulic, F ;
Queffelec, P ;
Bourbigot, C ;
LeMest, Y ;
Loaec, J ;
Beroual, A .
JOURNAL OF APPLIED PHYSICS, 1997, 81 (02) :882-890
[3]   Organic-inorganic dielectric multilayer systems as high reflectivity distributed Bragg reflectors [J].
Convertino, A ;
Valentini, A ;
Ligonzo, T ;
Cingolani, R .
APPLIED PHYSICS LETTERS, 1997, 71 (06) :732-734
[4]   Organic multilayers as distributed Bragg reflectors [J].
Convertino, A ;
Valentini, A ;
Cingolani, R .
APPLIED PHYSICS LETTERS, 1999, 75 (03) :322-324
[5]  
DILKS A, 1981, ELECT SPECTROSCOPY T, V4
[6]  
DOYLE FJ, 1993, ADV POLYM SCI, V2
[7]  
DOYLE FJ, 1993, ADV POLYM SCI, V1
[8]   Molecular simulation of polymeric networks and gels: phase behavior and swelling [J].
Escobedo, FA ;
de Pablo, JJ .
PHYSICS REPORTS-REVIEW SECTION OF PHYSICS LETTERS, 1999, 318 (03) :86-112
[9]  
Flory P J., PRINCIPLES POLYM CHE
[10]   New findings on polypyrrole chemical structure by XPS coupled to chemical derivatization labelling [J].
Malitesta, C ;
Losito, I ;
Sabbatini, L ;
Zambonin, PG .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1995, 76 :629-634