Catalytic hydrogenation of 2,4-dinitrotoluene over a Pd/C catalyst: Identification of 2-(hydroxyamino)-4-nitrotolnene (2HA4NT) as reaction intermediate

被引：17

作者：

Neri, G

Musolino, MG

Rotondo, E

Galvagno, S

机构：

[1] UNIV MESSINA,DEPT IND CHEM,I-98166 MESSINA,ITALY

[2] UNIV REGGIO CALABRIA,FAC ENGN,I-89100 REGGIO CALABRIA,ITALY

[3] UNIV MESSINA,DEPT INORGAN CHEM ANALYT & MOL STRUCT,I-98166 MESSINA,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 111卷 / 03期

关键词：

palladium; 2,4-dinitrotoluene; hydrogenation;

D O I：

10.1016/1381-1169(96)00112-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic hydrogenation of 2,4-DNT over palladium supported on carbon catalysts is reported. The 2-(hydroxyamino)-4-nitrotoluene (2HA4NT) was identified as a reaction intermediate. The characterization of this compound and the reasons for its formation are discussed.

引用

页码：257 / 260

页数：4

共 7 条

[1]

BRAND K, 1923, BER DEUT CHEM GES, V55, P883

[2] KINETICS OF THE CATALYTIC-HYDROGENATION OF 2,4-DINITROTOLUENE .1. EXPERIMENTS, REACTION SCHEME, AND CATALYST ACTIVITY [J].