Synthesis and structural characterization of stable hydride-alkylidene complexes of iridium(III)

被引：29

作者：

Alias, FM

Poveda, ML

Sellin, M

Carmona, E

Gutierrez-Puebla, E

Monge, A

机构：

[1] Univ Sevilla, CSIC, Dept Quim Inorgan, Inst Invest Quim, Seville 41092, Spain

[2] CSIC, Inst Ciencia Mat, E-28049 Madrid, Spain

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 19期

关键词：

D O I：

10.1021/om980313r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The protonation of the iridapyrrole complex Tp(Me2)(H)Ir[C(Me)=(Me)=NH] allows the isolation of the two possible stereoisomers of the chelating Ir-(III) alkylidene [Tp(Me2)(H)Ir(=C(Me)CH(Me)C(Me)=NH)] [BAr4'] (2; Ar' = 3,5-C6H3(CF3)(2)). They undergo easy and reversible hydride migration onto the electrophilic carbene atom.

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页码：4124 / 4126

页数：3

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